Skip to main content
MDCAT · Chemistry

Stoichiometry MCQs for MDCAT

25 practice MCQs on the mole concept, Avogadro's number, empirical and molecular formulas, limiting reagents and percentage yield. Every question has the correct answer and an explanation.

Start free — 20 questions

Stoichiometry is part of the MDCAT Chemistry syllabus. This page collects Stoichiometry MCQs in the style of past MDCAT papers — below are 12 of them with answers and explanations, and the full set of 25 questions is in the HighYield MDCAT QBank.

This chapter covers: the mole concept, Avogadro's number, empirical and molecular formulas, limiting reagents and percentage yield.

Stoichiometry MCQs with answers

Q1.How many 'Cl' (chlorine) atoms are in two moles of chlorine?

  • A.2 × 6.02 × 10⁻²³ atoms
  • B.35.5 × 6.02 × 10²³ atoms
  • C.2 × 10²³ atoms
  • D.2 × 6.02 × 10²³ atoms
Show answer

Correct answer: D. 2 × 6.02 × 10²³ atoms

Two moles of chlorine atoms contain 2 × 6.02 × 10^23 atoms, applying Avogadro's number to the given number of moles.

Q2.When 8 grams (4 moles) of H₂ react with 2 moles of O₂, how many moles of water will be formed?

  • A.Five
  • B.Four
  • C.Six
  • D.Three
Show answer

Correct answer: B. Four

Since H2 and O2 react in a 2:1 ratio (2H2 + O2 to 2H2O), 4 moles of H2 fully reacting with the available O2 produces 4 moles of water.

Q3.How many moles of sodium are present in 0.1 g of sodium?

  • A.4.3 × 10⁻³
  • B.4.03 × 10⁻¹
  • C.4.01 × 10⁻²
  • D.4.3 × 10⁻²
Show answer

Correct answer: A. 4.3 × 10⁻³

0.1 g of sodium (atomic mass ≈ 23 g/mol) corresponds to 0.1/23 ≈ 4.3×10^-3 moles.

Q4.Mole fraction of any compound is the ratio of moles of all components in a:

  • A.Compound
  • B.Solution
  • C.Molecule
  • D.Solid
Show answer

Correct answer: B. Solution

Mole fraction is defined as the ratio of the moles of one component to the total moles of all components present in a solution.

Q5.Given solution contains 16.0 g of CH₃OH, 92.0 g of C₂H₅OH and 36 g of water. Which statement about mole fraction of the components is true?

  • A.Mole fraction of CH₃OH is highest
  • B.Mole fraction of C₂H₅OH and H₂O is the same
  • C.Mole fraction of CH₃OH and C₂H₅OH is same
  • D.Mole fraction of H₂O is the lowest among all
Show answer

Correct answer: B. Mole fraction of C₂H₅OH and H₂O is the same

Converting each component to moles (CH3OH ≈ 0.5 mol, C2H5OH = 2.0 mol, H2O = 2.0 mol) shows that the mole fractions of ethanol and water are equal, since they have the same number of moles.

Q6.A compound of sodium oxide has 74.2% of sodium and 25.8% of Oxygen. The empirical formula of the compound is?

  • A.Nao
  • B.NaO2
  • C.Na2O
  • D.Na2O2
Show answer

Correct answer: C. Na2O

Let’s find the empirical formula step-by-step 👇1️⃣ Assume 100 g of the compound → Na = 74.2 g, O = 25.8 g2️⃣ Convert to moles: Na = 74.2 ÷ 23 = 3.23 mol O = 25.8 ÷ 16 = 1.61 mol3️⃣ Find the simplest ratio: Na : O = 3.23 ÷ 1.61 : 1.61 ÷ 1.61 = 2 : 1✅ Empirical formula = Na₂O

Q7.If phenol is treated with 3 moles of conc. HNO₃ in the presence of H₂SO₄, what will be the product?

  • A.o-nitrophenol
  • B.p-nitrophenol
  • C.o-nitrophenol and p-nitrophenol
  • D.picric acid
Show answer

Correct answer: D. picric acid

Picric acid: Correct answer—When phenol is treated with concentrated nitric acid in the presence of sulfuric acid, it undergoes nitration, leading to the formation of picric acid (2,4,6-trinitrophenol), which is the major product.

Q8.The same moles of H2, N2, and O2 are present in 0.1 cc volume at STP. Which one has the greatest number of molecules:

  • A.N2
  • B.H2
  • C.O2
  • D.Number of molecules are equal
Show answer

Correct answer: D. Number of molecules are equal

The number of molecules is given by the formula:Number of molceules = moles x avogadros constantSince all of the given elements have the same number of moles all of them will have the same number of molecules, which will be 6.02 x 1023, the Avogadros constant.

Q9.The number of moles in an element is directly proportional to:

  • A.Mass of an element
  • B.Empirical formula mass
  • C.Molar mass of an element
  • D.Formula mass
Show answer

Correct answer: A. Mass of an element

​Since molar mass is constant for a given element, increasing the mass increases the number of moles proportionally. For example, doubling the mass of an element doubles the number of moles, making them directly proportional.

Q10.The enthalpy change when 1 Mole of water is formed by the reaction of acid with an alkali under standard conditions is known as:

  • A.Enthalpy of formation
  • B.Enthalpy of reaction
  • C.Enthalpy of combustion
  • D.Enthalpy of neutralization
Show answer

Correct answer: D. Enthalpy of neutralization

The enthalpy of neutralization is the specific enthalpy change when one mole of water is formed from the reaction of an acid and a base (alkali) under standard conditions.

Q11.Oxygen can be prepared by the decomposition of potassium chlorate (KClO3). How many moles of oxygen (O2(g)) can be formed by taking 12 moles of potassium chlorate (KClO3) according to the following equation?2KClO3(l) + heat --> 2KCl(s) + 3O2(g)

  • A.12 moles of oxygen
  • B.15 moles of oxygen
  • C.18 moles of oxygen
  • D.21 moles of oxygen
Show answer

Correct answer: C. 18 moles of oxygen

Option C is correct. The balanced chemical equation is: 2 KClO3(l) + heat → 2 KCl(s) + 3 O2(g). This indicates that for every 2 moles of KClO3, 3 moles of O2 are produced. To find out how many moles of O2 are produced from 12 moles of KClO3, we set up the following calculation: 12 moles KClO3 * (3 moles O2 / 2 moles KClO3) = 18 moles O2. Therefore, the answer is 18 moles of oxygen. The other options are incorrect because they do not align with the stoichiometry of the reaction. Specifically, options A, B, and D propose amounts of O2 that exceed or do not reach the correct product ratio based on the given moles of KClO3.

Q12.The number of particles (atoms, molecules, tons) in one mole of any substance is numerically equal to

  • A.6.023x10^22
  • B.6.023x10^21
  • C.6.023x10 ^23
  • D.4.02x10^23
Show answer

Correct answer: C. 6.023x10 ^23

One mole of any substance contains 6.023 x 10^23 particles (atoms, molecules, or ions). This number is known as the Avogadro's number (NA).Avogadro's number is a fundamental constant in chemistry, and it is used to relate the amount of a substance to the number of particles it contains.

Practise all 25 Stoichiometry questions

Start with 20 free questions — no card required. Unlock the full MDCAT QBank for chapter-wise drilling, timed tests and mock exams.

More MDCAT Chemistry chapters

All MDCAT chapter-wise MCQs →