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MDCAT · Chemistry

Periodic Table and Periodicity MCQs for MDCAT

27 practice MCQs on periodic trends, s-, p- and d-block elements, halogens, alkali metals and transition elements. Every question has the correct answer and an explanation.

Start free — 20 questions

Periodic Table and Periodicity is part of the MDCAT Chemistry syllabus. This page collects Periodic Table and Periodicity MCQs in the style of past MDCAT papers — below are 12 of them with answers and explanations, and the full set of 27 questions is in the HighYield MDCAT QBank.

This chapter covers: periodic trends, s-, p- and d-block elements, halogens, alkali metals and transition elements.

Periodic Table and Periodicity MCQs with answers

Q1.The elements for which the value of ionization energy is low, can:

  • A.Gain electrons readily
  • B.Gains electron with difficulty
  • C.Loss electrons less readily
  • D.Lose electrons readily
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Correct answer: D. Lose electrons readily

Elements with low ionization energy lose electrons readily, since less energy is required to remove an electron from their outer shell.

Q2.Melting points of group II-A elements are higher than those of group I-A because:

  • A.Atoms of II-A elements have smaller size
  • B.II-A elements are more reactive
  • C.Atoms of II-A elements provide two binding electrons
  • D.I-A elements have smaller atomic radius
Show answer

Correct answer: C. Atoms of II-A elements provide two binding electrons

Group II-A (alkaline earth) atoms contribute two valence electrons to metallic bonding, creating stronger metallic bonds and higher melting points than the singly-bonding Group I-A metals.

Q3.Alkaline earth metal hydroxides decompose on heating. Which of the following reactions is a correct representation of this decomposition?

  • A.M(OH)₂(s) → MO(s) + H₂O(l)
  • B.MOH(s) → M₂O(s) + H₂O(l)
  • C.2MOH₂(s) → 2MO(s) + H₂(l)
  • D.4MOH(s) → 4M(s) + 2H₂O(l) + O₂
Show answer

Correct answer: A. M(OH)₂(s) → MO(s) + H₂O(l)

Alkaline earth metal hydroxides decompose on heating according to M(OH)2(s) to MO(s) + H2O(l), releasing water and forming the metal oxide.

Q4.On the basis of oxidizing power of halogens, which reaction is possible?

  • A.I₂ + 2Cl⁻ → Cl₂ + 2I⁻
  • B.Br₂ + 2I⁻ → I₂ + 2Br⁻
  • C.Cl₂ + 2F⁻ → F₂ + 2Cl⁻
  • D.I₂ + 2Br⁻ → Br₂ + 2I⁻
Show answer

Correct answer: B. Br₂ + 2I⁻ → I₂ + 2Br⁻

Br2 can oxidize iodide ions to iodine (Br2 + 2I- to I2 + 2Br-), since bromine is a stronger oxidizing agent than iodine, making this reaction feasible based on the halogens' relative oxidizing power.

Q5.Which of the following is a typical transition element?

  • A.Sc
  • B.Y
  • C.Co
  • D.Ra
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Correct answer: C. Co

Y (yttrium) is a typical transition element because it belongs to the transition metals group in the periodic table. Transition elements are characterized by their partially filled d-orbitals in one or more of their oxidation states.

Q6.Which one of the following does not belong to Alkaline earth metals?

  • A.Be
  • B.Ra
  • C.Ba
  • D.Rn
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Correct answer: D. Rn

Radon is a chemical element with the symbol Rn and atomic number 86. It is a noble gas, not an alkaline earth metal. Radon is a radioactive gas that is colorless, odorless, and tasteless. It is formed as a decay product of uranium and thorium in the Earth's crust. Radon is known for being a health hazard due to its radioactivity and potential to accumulate in enclosed spaces.

Q7.Which of the following is a non-typical Transition element?

  • A.Cr
  • B.Mn
  • C.Zn
  • D.Fe
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Correct answer: C. Zn

Zinc is not considered a typical transition element because it lacks partially filled d orbitals in its neutral or common oxidation states. It typically exhibits a +2 oxidation state, with a completely filled d orbital, resembling more like an s-block element in terms of electronic configuration.

Q8.Group VIB of transition metal contains:

  • A.Zn, Cd, Hg
  • B.Fe, Ru, Os
  • C.Cr, Mo, W
  • D.Mn, Te, Re
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Correct answer: C. Cr, Mo, W

Group VIB of transition elements contains: Cr, Mo, W

Q9.Which group of the periodic table contain non-metals, metalloids and metals

  • A.I B
  • B.VII A
  • C.IV A
  • D.VI A
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Correct answer: C. IV A

Group IV-A of the periodic table, also known as Group 14, contains elements that include non-metals, metalloids, and metals.

Q10.Why does fluorine have less electron affinity as compared to bromine?

  • A.Electronegativity
  • B.Thick, small electronic cloud
  • C.Seven electrons in outermost shell
  • D.Higher ionization energy
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Correct answer: B. Thick, small electronic cloud

Fluorine has less electron affinity compared to bromine primarily due to its small atomic size and the associated compact 2p subshell, which leads to greater electron-electron repulsion when an extra electron is added. Additionally, the high electronegativity of fluorine reflects its tendency to hold onto its electrons tightly, which can also affect its affinity for extra electrons. In contrast, bromine's larger size reduces the repulsion experienced when an additional electron is added, resulting in a more favorable electron affinity.

Q11.The difference of lithium from the other alkali metals is mainly because of:

  • A.Large radius and low charge density
  • B.Small radius and low charge density
  • C.Large radius and high charge density
  • D.Small radius and high charge density
Show answer

Correct answer: D. Small radius and high charge density

Correct, as lithium has the smallest atomic size in the alkali metal group, leading to high charge density, which makes it behave differently from other alkali metals (e.g., stronger covalent character in compounds and diagonal relationship with magnesium).

Q12.Flame tests identify alkali metals when they are burnt, which of the combinations given is the correct one?

  • A.Li: Red
  • B.Na: Lilac
  • C.K: Red
  • D.Cs: Yellow
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Correct answer: A. Li: Red

Flame tests are used to identify alkali metals based on the characteristic colors they produce when burned:- Lithium (Li): Red- Sodium (Na): Yellow- Potassium (K): Violet- Caesium (Cs): Blue

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